EXTRACTION AND DETERMINATION OF THE PHYSICAL CHEMICAL PROPERTIES OF CASHEW NUT OIL

CHAPTER
ONE

INTRODUCTION

        

The
cashew nut (Anacadium Occidentale) produces nuts, the Kernels of which have
increase considerably in economic importance over the past few decades.
Indigenous to Brazil. The cashew was taken to West Africa, East and India by
the Portuguese in the 15th and 6th centuries. It was noticed
that the tree grew well on poor sandy soils along the costal belt and was used
by the Portuguese in Africa as an anti soil, erosion measure the tree prospered
and spread naturally, particularly in East Africa and India and the progeny of
these wild cashew has formed the basis of the raw material for the cashew
industry. Through the plant was primarily intended for checking soil erosion,
it is now mainly grown for its commercially important kernel and shell oil.
(Tiyadurai 1963).

        Cashew
nut is a high value edible nut. It yield two oils one of these found between
the seed coat (or pericare) and the nut, is called the cashew nut shell liquid
(CNSC). It is used in industry as a raw material for brake lining compounds, as
a water proofing agent, a preservative and in the manufacturing of paints and
plastics. Iy is toxic and corrosive to the skin. (Cashew applies are sometimes
made locally in to fruit drinks, wines and pickles.

        The
fat of nut is completely naturally and unprocessed which is best for the body.
It is especially rich in Linoleic acid (omega-3) and is least damaging to heart
and arteries. Infact, it constitutes about 47% of the total weight of the nut.
Nut often produce oil half their weight. It could be good news for people who
feel week debilitated. Cashew has the right combination of fat and the ratio
consumption. The relative abundance of monounsaturated fatty acids in cashew
nut is conducive to the promotion of good health and that the relative
abundance of fat is cashew nut in no way poses a nutritional risk (Achal 2005).
The advantages of cashew kernel is that it has a rich, delightful taste and it
meaty and acceptable as it.

NUTRITIVE
VALUE/COMPOSITION


        Cashew
is a highly nutritious and concentrated form of food, providing a substantial
amount of energy. The cashew nut kernel has a pleasant taste and flavor and can
be eaten raw, fried and sometimes salted or sweetened with sugar (manay et al,
1987). It also contributes as an important source of invisible fat in the diet,
being widely used in a variety of ways there has been a growing demand for
cashew. The nut contains an acid compound which is a powerful vesicant, which
is abrasive to the skin. There has been a growing demand for cashew in many
temperate countries where the demand is increasing (Russel, 1979).

1.1.1        OVERALL COMPOSITION


        The
kernel is considered to be of high nutritive quality and growing conditions or
the variety of cashew may have an influence on kernel composition (Ohler,
1979). The overall composition of the kernel is protein 21%, fat 46% and
carbohydrate 25%.

 1.1.2       TOTAL
NUTRIENT CONTENT


        The
total nutrient value of 100g of cashew nut is presented in table 1.

Moisture is 5.9

Total mineral = 2.4

Total fibre = 1.3

Energy = 785

Protein = 24

Carbohydrate = 41

Thiamin = 0.63

Niacin = 2.5

Vitamin K  = 650

Total fate = 64

Saturated = 12.9

Unsaturated
(linoleic) = 10.2

Ca = 53

P = 52.2

Fe = 5.3

Riboflarin = 0.19

Beta – Carotene = 60

Retinol Equivalent =
331u;10mcg


1.1.3        PROTEIN CONTENT


        Wide
differences in the protein content ranging from 13.13 to 25.03% have been
reported from various region of India.

It has been
suggested that protein content be considered as one of the most important
factors in future breeding and selection programs on cashew nut. The Amino acid
composition of kernel protein has been reported by various experts. (Tabel 2)
Amino-Acid composition of cashew kernel protein.


Glutamic Acid = 28.0

Leucine = 11.93

Iso levcine = 3.86

Alanine = 3.18

Phenylalanire = 4.35

Tyrosine = 3.20

Glycine = 5.20

Histidine = 1.81

Lysine  = 3.32

Methionine = 1.30

Cystine = 1.02

Threonine = 2.78

Valine = 4.53

Tryptophane = 1.37

Aspartic Acid = 10.78

Proline = 3.72

Serine = 5.76



1.1.4        CARBOHYDRATE CONTENT


        Analysis
of cashew nut kernels from different region of India have revealed that there
are variation in the reducing sugar content from 1% to 3% and the non-reducing
sugar from 2.4% to 8.7% starch content ranged from 4.6 % to 11.2% and the oil
content also showed a wide variability from 34.5% to 46.8%.



1.1.5        FATTY ACID COMPOSITION


        The
fat and oil content of cashew nut contribute substantially to its energy
content and consist mostly of glycerides of Oleic acid (73.8%) and linoleic acid
(7.7%) (Ohler, 1979). Table 3 gives the composition of fats in cashew kernels.

Table 3: Fatty and composition of
Cashew kernel (%)

Oleic Acid 73.3

Linoleic acid 7.67

Palmitic Acid 0.89

Steric Acid 11.24

Lignoseric Acid 0.15

Unsciponifiable matter 0.42



1.1.6        VITAMIN CONTENT


        1.1.7    

Ca = 0.04

P = 0.88

Na = 0.005

K = 0.57

mg = 0.28

fe = 0.0008

Cu = 0.002

Zn = 0.004

Mn = 0.02

 


 1.2  USES
OF CASHEW NUT OIL


        The
cashew Nut shell (CNS2), a byproduct of processing cashew, is mostly
composed of anacardic acid (Alexandra 2000) (70%) cardol (18%) and cardanol
(5%) (A.B, 2012). These acid have been used effectively against 100th
abscesses due to their lethality to a wide range of gram –position bacteria
many part of the plant are used by the patamona of Guyana medicinally. The bark
is scraped and soaked overnight or boiled as an antidiarrheal; it also yields a
gum used in varnish. Seeds are ground into powder used for antiveran for snake
bites; the nut oil is used topically as an antifungal and for healing cracked
heels.

        Anacarde
acid is also used in the chemical industry for the production of cardanol,
which is used for resins, coating, and frictional material. (Alenxandre 2008)
cashew nut is a popular snack and it is rich flavor means that it is often
eaten roasted, on its own, lightly salted or tree nuts, containing starch to
about 10% of their weight. This makes them more effective than other nuts in
thickening water-based dishes such as soup, meat stews and some India milk based
deserts. Many South East Asia and South Asian cuisines use cashew for this
unusual characteristic, rather than other nuts. (Harold Mc Gee 2004).

        The
shell of the cashew is toxic, which is why the cashew is shelled before it is
sold to consumers.


1.3   POTENTIAL OF CASHEW CULTIVATION


        The
cashew tree (Anacardium Occidentale) was brought to India by Portuguese in 1653
AD from eastern Brazil. Then is spread across almost all parts of the country
and now it is among the top 3 commercial crops as per cashew statistic book
(2001). Cashew tree is evergreen and relatively easy to cultivate. It grows up
to 12 meters high and has a spread of 25 meters, most frequently found in coastal
areas.

Table 1: Cashew nut production
worldwide year 2000 – Jason. W Clay (2004)

Country

Area hectares

Cashew nut
103tons/year

India

837,000

537

Brazil

598,000

114

Nigeria

291,000

184

Indonesia

260,000

91

Guinea Bissau

210,000

73

Benin

175,000

26

Vietnam

151,000

27

Coted’ivore

125,000

78

Tanzania

90,000

121

World

2,742,000

1,600

 

Table 2: All India area, production
and yield of cashew nut (directorate of cashew nut and cocoa development, Cochin,
Kerala 2011 report).

Year

Cashew Cultivated
area 1000 hectares

Production area 1000
hectares

Cashew Production
1000 tons

Cashew yield kg per
hectare

2001-02

837,000

666

470

710

2002-03

598,000

675

550

760

2003-04

291,000

684

535

800

2004-05

260,000

700

544

810

2005-06

210,000

760

573

815

2006-07

175,000

765

620

820

2007-08

151,000

770

665

860

2008-09

125,000

835

695

773

                            


1.4           CASHEW NUT SHELL COMPOSITION AND
PROPERTIES


The cashew nut
shell is about 0.3cm thick, hang a soft feathery outer skin and hard inner skin
between these skins is the honey comb structure contain CNSL ln side the shell
is the our kernel wrapped in at thin skin know as the testa CNS is a reddish
brown viscous liquid, having (4) major components: Anacardic acid, cardonl,
methy1 cardol which are naturally occurring unstrurated phenols (NSL is
traditionally obtained as a byproduct during the process of removing the cashew
kernel from the nut. The process used are mainly hot oil and roasting in which
the cash out from the shell.

Natural (i.e
cold, solvent extracted) (NSL is a liquid that contain approximately 70%
anacardic acid, 18% cardol and 5% cardanol, with the remainder being made up of
other phenols and less polar substance (m 9 to 5, J.E.X etal, 2009). As can be
seen in figure 2, anacardic acid, cardanol and cardol consist of mixture of
compound having various degrees of instauration in the allyside chain.

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