Give the formula indicating the relationship between entropy, free energy and enthalpy changes of…

(a) Give the formula indicating the relationship between entropy, free energy and enthalpy changes of a system.

(b) For each of the following, state whether entropy change is positive, negative or zero.

(i) H(_2)O(_{(g)}) -> H(_2)O(_{(g)})

(ii) Cl(_{2(g)}) —> 2CI(_{(g)})

(iii) HCI(_{(g)}) -> HCl(_{(g)})

Explanation

(a) (Delta)C            =           (Delta)H       –         T(Delta)S

(free energy)   (enthalpy)      (Temperature x Entropy)

(b)(i) Entropy is positive

(ii) Entropy is positive

(iii) Entropy is negative.

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