20 cm3 of 1.0 molar NH4OH solution when neutralized with 20.05cm3 of 0.1 molar HCl…

20 cm3 of 1.0 molar NH4OH solution when neutralized with 20.05cm3 of 0.1 molar HCl liberated -102 joules of heat. Calculate the heat of neutralization of NH4OH?
  • A.
    -51.O KJ mol–
  • B.
    +57.3 KJ mol–
  • C.
    +57.O KJ mol–
  • D.
    +51.0 KJ mol–
Correct Answer: Option A
Explanation

NH4OH = 20cm of 0.1 m
NH4 + HCl → NH4Cl = H2O
Heat of Neutralization of NH4OH
= (frac{-102}{2}) = -51.0 KJ mole-1

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